文献类型：期刊文献

英文题名：Adsorption dynamics and mechanism of aqueous sulfachloropyridazine and analogues using the root powder of recyclable long-root Eichhornia crassipes

作者：Liu, Lin[1]; Hu, Shuangqing[2]; Shen, Genxiang[2]; Farooq, Usman[1]; Zhang, Wei[1]; Lin, Sen[1]; Lin, Kuangfei[1]

机构：[1] State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai, 200237, China; [2] Shanghai Academy of Environmental Sciences, Shanghai, 200233, China

年份：2018

卷号：196

起止页码：409

外文期刊名：Chemosphere

收录：EI(收录号：20180204629757)

语种：英文

外文关键词：Amides - Sulfur compounds - Boundary layers - Physisorption

摘要：In this study, we reclaimed the root powder of long-root Eichhornia crassipes (L.R.E.C.) as a biosorbent to remove aqueous sulfachloropyridazine (SCP) and other sulfonamides. The adsorption processes were investigated dependent on multiple measurements, including FT-IR and XPS analysis. The results confirmed that the basic amine group of neutral SCP molecules and the carboxyl hydroxyl on the surface of the root powder played the leading role in adsorption processes. Additionally, the experiments of ionic strength effect validated the involvement of electrostatic interaction in adsorption. Meanwhile, the adsorption data were fitted by various models and the results indicated that the Pseudo-second-order model and Freundlich model could well describe the adsorption processes, indicating the existence of physisorption and chemisorption as multi-layer adsorption. The maximum capacities of root powder for SCP were calculated to be 226.757 μg g?1 (288.15 K), 182.815 μg g?1 (303.15 K) and 163.132 μg g?1 (318.15 K) at pH of 3.0. The thermodynamic results revealed that the adsorption was a spontaneous and exothermic process. Moreover, the accordance with intra-particle diffusion presented that the adsorption processes could be divided into three steps and the reaction constant had a negatively linear relationship with the thickness of the boundary layer. The results proved that root powder of L.R.E.C. has great potential to remediate sulfonamides at practical level. ? 2018 Elsevier Ltd