文献类型：期刊文献

中文题名：ZnO@MOF@PANI core-shell nanoarrays on carbon cloth for high-performance supercapacitor electrodes

英文题名：ZnO@MOF@PANI core-shell nanoarrays on carbon cloth for high-performance supercapacitor electrodes

作者：Chunmei Zhu[1];Ying He[1];Yijun Liu[1];Natalia Kazantseva[2];Petr Saha[2];Qilin Cheng[1,2]

机构：[1]Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology,Shanghai 200237, China;[2]Centre of Polymer Systems, Tomas Bata University in Zlin,nam. T. G. Masaryka 5555, 760 01 Zlin, Czechia

年份：2019

卷号：28

期号：8

起止页码：124

中文期刊名：Journal of Energy Chemistry

外文期刊名：能源化学（英文版）

收录：CSTPCD;;Scopus;CSCD:【CSCD2019_2020】；

基金：supported by the National Key R&D Program of China(2016YFE0131200);the National Natural Science Foundation of China(51702098);International Cooperation Project of Shanghai Municipal Science and Technology Committee(15520721100,18520744400);Research Program supported by the Ministry of Education,Youth,and Sports of the Czech Republic(LTACH17015)

语种：英文

中文关键词：Metal-oragnic;framework;Polyaniline;Core-shell;nanoarrays;Supercapacitor;Electrochemical;properties

外文关键词：Metal-oragnic framework;Polyaniline;Core-shell nanoarrays;Supercapacitor;Electrochemical properties

摘要：Hierarchical ZnO@metal-organic framework @polyaniline(ZnO@MOF@PANI) core-shell nanorod arrays on carbon cloth has been fabricated by combining electrodeposition and hydrothermal method. Well-ordered Zn O nanorods not only act as a scaffold for growth of MOF/PANI shell but also as Zn source for the formation of MOF. The morphology of ZnO@MOF@PANI composite is greatly influenced by the number of PANI electrodeposition cycles. Their structural and electrochemical properties were characterized with different techniques. The results indicate that the Zn O@MOF@PANI with 13 CV cycles of PANI deposition demonstrates the maximum specific capacitance of 340.7 F g-1 at 1.0 A g-1, good rate capability with84.3% capacitance retention from 1.0 to 10 A g-1 and excellent cycling life of 82.5% capacitance retention after 5000 cycles at high current density of 2.0 A g-1. This optimized core-shell nanoarchitecture endows the composite electrode with short ion diffusion pathway, rapid ion/electron transfer and high utilization of active materials, which thus result in excellent electrochemical performance of the ternary composite.
Hierarchical ZnO@metal-organic framework @polyaniline（ZnO@MOF@PANI） core-shell nanorod arrays on carbon cloth has been fabricated by combining electrodeposition and hydrothermal method. Well-ordered Zn O nanorods not only act as a scaffold for growth of MOF/PANI shell but also as Zn source for the formation of MOF. The morphology of ZnO@MOF@PANI composite is greatly influenced by the number of PANI electrodeposition cycles. Their structural and electrochemical properties were characterized with different techniques. The results indicate that the Zn O@MOF@PANI with 13 CV cycles of PANI deposition demonstrates the maximum specific capacitance of 340.7 F g-1 at 1.0 A g-1, good rate capability with84.3% capacitance retention from 1.0 to 10 A g-1 and excellent cycling life of 82.5% capacitance retention after 5000 cycles at high current density of 2.0 A g-1. This optimized core-shell nanoarchitecture endows the composite electrode with short ion diffusion pathway, rapid ion/electron transfer and high utilization of active materials, which thus result in excellent electrochemical performance of the ternary composite.