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Green Synthesis of Iron(Ⅱ,Ⅲ)-polyphenol Nanoparticles and Their Adsorption of Malachite Green    

文献类型:期刊文献

中文题名:Green Synthesis of Iron(Ⅱ,Ⅲ)-polyphenol Nanoparticles and Their Adsorption of Malachite Green

作者:胡玉[1];ZHOU Fan[2];ZHANG Nan[1];PAN Xiaobin[2];LI Shiying[1];ZHANG Dong[2];LI Li[1];张玲帆[3]

机构:[1]Department of Chemistry and Environmental Engineering,Hanjiang Normal University,Shiyan 442000,China;[2]Shiyan Hydrological and Water Resources Survey Bureau of Hubei Province,Shiyan 442000,China;[3]School of Chemistry and Molecular Engineering,East China University of Science and Technology,Shanghai 200237,China

年份:2024

卷号:39

期号:4

起止页码:1025

中文期刊名:Journal of Wuhan University of Technology(Materials Science)

外文期刊名:武汉理工大学学报(材料科学英文版)

收录:CSTPCD;;Scopus;CSCD:【CSCD2023_2024】;PubMed;

基金:Funded by the Hubei Provincial Natural Science Foundation of China(No.2024AFB946);the Excellent Young and Middle-aged Science and Technology Innovation Team Plan of Hubei Colleges(No.T201824)。

语种:中文

中文关键词:iron;nanoparticles;pomegranate;green tea;mulberry;adsorption

摘要:Three kinds of iron nanoparticles(FeNPs)were prepared via green route based on pomegranate(PG),green tea(GT),and mulberry(ML)extracts under ambient conditions.The obtained materials were characterized by scanning electron microscopy(SEM),transmission electronic microscopy(TEM),X-ray energy-dispersive spectrometer(EDS),X-ray diffraction(XRD),fourier transform infrared spectroscopy(FTIR),and X-ray photoelectron spectroscopy(XPS)techniques.The experimental results show that FeNPs were in the form of amorphous iron(Ⅱ,Ⅲ)-polyphenol complex with different dispersity and morphologies.GT-Fe has the smallest size range of 25-35 nm,PG-Fe has a moderate size-distribution of 30-40 nm,while ML-Fe formed a tuberous net-type with a sheeting structure.PG-Fe displays the highest removal efficiency of 90.2%in 20 min towards cationic dye of malachite green(16.6%by ML-Fe and 69.3%by GT-Fe),which is attributed to its highest polyphenol content,lowest zeta potential,as well as the most Fe^(2+)on the surface of FeNPs.The removal mechanism was mainly induced by electrostatic adsorption based on pH and zeta potential tests.

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