文献类型：期刊文献

英文题名：Selective One-Pot Production of High-Grade Diesel-Range Alkanes from Furfural and 2-Methylfuran over Pd/NbOPO4

作者：Xia, Qineng[1];Xia, Yinjiang[1];Xi, Jinxu[1];Liu, Xiaohui[1];Zhang, Yongguang[2];Guo, Yong[2];Wang, Yanqin[1]

机构：[1]East China Univ Sci Technol, Shanghai Key Lab Funct Mat Chem & Res, Inst Ind Catalysis, Sch Chem & Mol Engn, 130,Meilong Rd, Shanghai 200237, Peoples R China;[2]SINOPEC, Res Inst Petr Proc, 18,Xueyuan Rd, Beijing 100083, Peoples R China

年份：2017

卷号：10

期号：4

起止页码：747

外文期刊名：CHEMSUSCHEM

收录：;EI(收录号：20165103142771);WOS:【SCI-EXPANDED(收录号:WOS:000397006500014)】；

基金：The research was sponsored financially by the National Natural Science Foundation of China (No. 91545103, 21273071 and 21403065), China Postdoctoral Science Foundation(2016M590328) and the Science and Technology Commission of Shanghai Municipality (10dz2220500).

语种：英文

外文关键词：alkanes; alkylation; diesel; furfural; hydrodeoxygenation

摘要：A one-pot method for the selective production of high-grade diesel-range alkanes from biomass-derived furfural and 2-methylfuran (2-MF) was developed by combining the hydroxyalkylation/alkylation (HAA) condensation of furfural with 2-MF and the subsequent hydrodeoxygenation (HDO) over a multifunctional Pd/NbOPO4 catalyst. The effects of various reaction conditions as well as a variety of solid-acid catalysts and metal-loaded NbOPO4 catalysts were systematically investigated to optimize the reaction conditions for both reactions. Under the optimal reaction conditions up to 89.1% total yield of diesel-range alkanes was obtained from furfural and 2-MF by this one-pot method.