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Synthesis of zincic phthalocyanine derivative functionalized with four peripheral tetrathiafulvalene units  ( SCI-EXPANDED收录)  

文献类型:期刊文献

英文题名:Synthesis of zincic phthalocyanine derivative functionalized with four peripheral tetrathiafulvalene units

作者:Hu, YY; Shen, YJ

机构:[1]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份:2002

卷号:39

期号:5

起止页码:1071

外文期刊名:JOURNAL OF HETEROCYCLIC CHEMISTRY

收录:;WOS:【SCI-EXPANDED(收录号:WOS:000178503400035),CCR-EXPANDED(收录号:WOS:000178503400035)】;

语种:英文

摘要:A zincic phthalocyanine (Pc) derivative functionalized with four peripheral substituted tetrathiafulvalene (TTF) units has been synthesized. The intermediates and target compound have been characterized by H-1-nmr, C-13-nmr, ms, EA, uv-vis and mp. The molecular weight of H2Pc-TTF4 can not be found in mass spectra. H-1-nmr spectra and mp determination show both H2Pc-TTF4 and ZnPc-TTF4 are isomer-mixtures. Uv-vis spectra indicate that the aggregation of H2Pc-TTF4 is solvent dependent and the introduction of Zn atom affects the solubility of the assembly.

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