文献类型：期刊文献

中文题名：顺酐在负载型镍钼催化剂上高压液相加氢合成1,4-丁二醇本征动力学的研究

英文题名：STUDY OF THE LIQUID PHASE HYDROGENATION KINETICS OF MALEIC ANHYDRIDE OVER SUPPORTED Ni-Mo CATALYST

作者：林川[1];吴指南[1]

机构：[1]华东化工学院

年份：1990

卷号：11

期号：2

起止页码：83

中文期刊名：Chinese Journal of Catalysis

外文期刊名：催化学报（英文）

收录：CSTPCD;;Scopus;北大核心:【北大核心1992】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：丁二醇;合成;顺酐;镍钼催化剂

摘要：在电磁搅拌式高压反应釜中研究了顺酐在负载型镍钼催化剂上高压液相加氢本征动力学。建立了顺酐加氢的反应网络,考察了反应温度、氢气压力对反应速率的影响,用线性或非线性最小二乘法求取了动力学参数,得到了动力学模型。模型验证表明,模型对实验数据的拟合是有效的。
The intrinsic kinetics of maleic anhydride hydrogenation over supported nickel-molybdenum catalyst was studied in a magnetic agitated autoclave. The reaction network of maleic anhydride hydrogenation was founded. The efffcts of reaction temperature and hydrogen pressure on the reaction rate were studied. The kinetic parameters were estimated in terms of linear or non-linear least square method and the kinetic models were obtained. The verification of the models showed that the models imitated the experimental data well.