文献类型：期刊文献

英文题名：Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties

作者：Zhang, Jun[1,2];Fu, Jun[1,2];Su, Xiaolong[1,2];Qin, Xinke[1,2];Zhao, Meixin[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2012

卷号：48

期号：77

起止页码：9625

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000308215500019)】；

基金：Financial support from Shanghai Pujiang Talent Program (11PJ1402500), the Fundamental Research Funds for the Central Universities (WK1114014), the Shanghai Municipal Committee of Science and Technology (08dj1400100-2), National Basic Research Program of China (973)-2010CB833302, and the National Natural Science Foundation of China (21171056, 21072206, 20472096, 20872162, 20672127, 20821002 and 20732008) is greatly acknowledged.

语种：英文

摘要：A series of new 2,3,5-triaryl-substituted oxazolium and thiazolium salts are readily prepared by a Tf2O-mediated intramolecular cyclisation and their use as precursors for the synthesis of novel oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes has been developed.