文献类型：期刊文献

中文题名：巯基乙酸锑配合物的合成与X射线粉末衍射数据指标化

英文题名：Synthesis and indexes of X-ray powder diffraction data of the complex of thioglycolic acid and trivalent antimonyion

作者：钟国清[1];郭应臣[2];陈娅如[3];栾绍嵘[3];杨新斌[1]

机构：[1]四川畜牧兽医学院基础部,重庆402460;[2]南阳师范学院化学系,河南南阳473061;[3]华东理工大学化学系,上海200237

年份：2002

卷号：14

期号：2

起止页码：199

中文期刊名：化学研究与应用

外文期刊名：Chemical Research and Application

收录：CSTPCD;;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：巯基乙酸;锑(Ⅲ)配合物;合成;射线粉末衍射;衍射数据指标化;晶体结构

外文关键词：thioglycolic acid;antimony(Ⅲ) complex;synthesis;index of X ray powder diffraction data

摘要：The novel complex of thioglycolic acid and trivalent antimony ion had been synthesized by liquid phase reaction of thioglycolic acid and antimony trichloride.The structure of the complex was characterized by elemental analyses and X ray powder diffraction.The complex has the composition of HSb(SCH 2COO) 2 being white crystal,stable in air,non hygroscopicity and decomposed above 208℃.The results of indexes to the X ray powder diffraction data indicate that the crystal structure of the complex belongs to monoclinic system.The lattice parameters are:a=1.4015nm,b=1.2092nm,c=1.2419nm,β=126.68°,V=1.6879nm 3,Z=8,D cal =2.384g·cm -3 ,D exp =2.374g·cm -3 .The calculated lattice parameters are in agreement with those of the single crystal determined by us.
The novel complex of thioglycolic acid and trivalent antimony ion had been synthesized by liquid phase reaction of thioglycolic acid and antimony trichloride.The structure of the complex was characterized by elemental analyses and X ray powder diffraction.The complex has the composition of HSb(SCH 2COO) 2 being white crystal,stable in air,non hygroscopicity and decomposed above 208℃.The results of indexes to the X ray powder diffraction data indicate that the crystal structure of the complex belongs to monoclinic system.The lattice parameters are:a=1.4015nm,b=1.2092nm,c=1.2419nm,β=126.68°,V=1.6879nm 3,Z=8,D cal =2.384g·cm -3 ,D exp =2.374g·cm -3 .The calculated lattice parameters are in agreement with those of the single crystal determined by us.