文献类型：期刊文献

英文题名：A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes

作者：Zhang, Fan[1,2];Cao, Xiao-Ming[3,4];Wang, Jiwei[1,2];Jiao, Jiajun[1,2];Huang, Yongming[1,2];Shi, Min[1,2,5];Braunstein, Pierre[6];Zhang, Jun[1,2]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, 130 Mei Long Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, 130 Mei Long Rd, Shanghai 200237, Peoples R China;[3]East China Univ Sci & Technol, Sch Chem & Mol Engn, Ctr Computat Chem, 130 Mei Long Rd, Shanghai 200237, Peoples R China;[4]East China Univ Sci & Technol, Sch Chem & Mol Engn, Res Inst Ind Catalysis, 130 Mei Long Rd, Shanghai 200237, Peoples R China;[5]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China;[6]Univ Strasbourg, CNRS, UMR 7177, CHIMIE,Lab Chim Coordinat, 4 Rue Blaise Pascal, F-67081 Strasbourg, France

年份：2018

卷号：54

期号：45

起止页码：5736

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000434314500015)】；

基金：Financial support from the National Natural Science Foundation of China (21671066, 21476071, 21673072, and 21171056) is greatly acknowledged.

语种：英文

摘要：Homo (Au-3)- and heterotrinuclear coinage metal complexes (Au2Ag and Au2Cu) ligated by the first tritopic carbanionic N-heterocyclic carbene (NHC) have been prepared by deprotonation of ditopic NHC digold complexes and structurally characterized by single-crystal X-ray diffraction.