文献类型：期刊文献

英文题名：Insights into size-dependent activity and active sites of Au nanoparticles supported on TS-1 for propene epoxidation with H2 and O2

作者：Feng, Xiang[1];Duan, Xuezhi[1];Qian, Gang[1];Zhou, Xinggui[1];Chen, De[2];Yuan, Weikang[1]

机构：[1]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;[2]Norwegian Univ Sci & Technol, Dept Chem Engn, N-7491 Trondheim, Norway

年份：2014

卷号：317

起止页码：99

外文期刊名：JOURNAL OF CATALYSIS

收录：;EI(收录号：20142917945422);WOS:【SCI-EXPANDED(收录号:WOS:000341473000011)】；

基金：This work is financially supported by the 973 Program (2012CB720501) and the 111 Project of Ministry of Education of China (B08021).

语种：英文

外文关键词：Propene epoxidation; Uncalcined TS-1; Size-dependent activity; Au active sites; Corner sites

摘要：Propene epoxidation with H-2/O-2 is a typical structure-sensitive reaction. For a given support containing tetra-coordinated Ti species such as TS-1, the catalytic activity is greatly influenced by supported Au nanoparticle size. The identification of size-dependent activity of Au catalyst was achieved over a series of Au nanoparticles (2.6-5.1 nm) deposited on the exterior surface of TS-1 by employing uncalcined TS-1. Through this approach, we could obtain very stable Au catalysts with distinguishable and uniform-sized Au particles, which are critical for structure-sensitivity analysis. The PO formation rate (mol(po) s(-1) mol(Au)(-1)) over these catalysts was found to vary with average Au diameter (d) as d(-2.7 +/- 0.3). Moreover, typical Au nanoparticles on uncalcined TS-1 appeared as truncated cuboctahedron with top facet of (1 1 1). Model calculations derived from the representative Au particle shape and the above size-dependent activity were then performed to show that corner sites of Au nanoparticles are dominant Au active sites for propene epoxidation. (C) 2014 Elsevier Inc. All rights reserved.