文献类型：期刊文献

英文题名：Practical way for the synthesis of phosphine oxides and phosphine sulfides from benzyl alcohol derivatives

作者：Ma, Yutao[1,2];Chen, Feng[1,2];Bao, Jifeng[5];Wei, Hao[3];Shi, Min[1,2,4];Wang, Feijun[1,2]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, 130 MeiLong Rd, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, 130 MeiLong Rd, Shanghai 200237, Peoples R China;[3]Shanghai Jiao Tong Univ, Sch Elect Informat & Elect Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China;[4]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China;[5]Shanghai Univ Tradit Chinese Med, Shuguang Hosp, 528 Zhangheng Rd, Shanghai 201203, Peoples R China

年份：2016

卷号：57

期号：23

起止页码：2465

外文期刊名：TETRAHEDRON LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000376835300001)，CCR-EXPANDED(收录号:WOS:000376835300001)】；

基金：The authors acknowledge the National Natural Science Foundation of China (21372075 and 61376003) and the Medical Engineering Crossover Fund of Shanghai Jiao Tong University (YG2015MS23) for financial support.

语种：英文

外文关键词：Ph2PI; Michaelis-Arbuzov reaction; Phosphine oxides; Phosphine sulfoxides; Oxophilic Lewis acid

摘要：The reaction of benzyl alcohol derivatives with Ph2PI generated in situ from Ph2PCl and NaI provides a facile way to the synthesis of pentavalent phosphine compounds with moderate to excellent yields. (C) 2016 Elsevier Ltd. All rights reserved.