文献类型：期刊文献

英文题名：3-Butyl-1-methylimidazolinium borohydride ([bmim][BH₄])-a novel reducing agent for the selective reduction of carbon-carbon double bonds in activated conjugated alkenes

作者：Wang, Jiayi[1];Song, Gonghua[1];Peng, Yanqing[1];Zhu, Yidong[1]

机构：[1]E China Univ Sci & Technol, Inst Pesticides & Pharmaceut, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China

年份：2008

卷号：49

期号：46

起止页码：6518

外文期刊名：TETRAHEDRON LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000260645900009)，CCR-EXPANDED(收录号:WOS:000260645900009)】；

基金：Financial support for this work from the NSFC (Grant 20676033), Shanghai Commission of Science and Technology and Shanghai Leading Academic Discipline Project (Project Number: B507) are gratefully acknowledged.

语种：英文

外文关键词：Reduction; Double bond; Ionic reducing reagent; Selective

摘要：A novel ionic reducing reagent 3-butyl-1-methylimidazolium borohydride ([bmim][BH4]), was synthesized and successfully used for the selective reduction of carbon-carbon double bonds in conjugated alkenes as well as the alpha,beta-carbon-carbon double bonds in highly activated alpha,beta,gamma,delta-unsaturated alkenes. The reagent can be regenerated and reused several times without losing its activity. (C) 2008 Elsevier Ltd. All rights reserved.