文献类型：期刊文献

中文题名：加压铜基催化剂上CO—H2合成甲醇本征动力学

英文题名：Intrinsic kinetics of methanol synthesis from CO-H2 over pressurized copper-base catalyst

作者：陈闽松[1];姚佩芳[1];房鼎业[1];朱炳辰[1]

机构：[1]华东化工学院

年份：1989

卷号：14

期号：6

起止页码：23

中文期刊名：天然气化工—C1化学与化工

外文期刊名：Natural Gas Chemical Industry

收录：CSTPCD;;北大核心:【北大核心1992】；CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：甲醇;合成;CO-H2;铜催化剂

摘要：用直流式等温积分反应器测试了在5MPa压力、C301铜基催化剂上CO-H_2合成甲醇的本征反应速率,用改进的牛顿-高斯法分别对幂函数型和L-H-H-W型的甲醇合成反应本征动力学模型进行了参数估值,得到了动力学方程。实验与计算结果表明,两种模型都是适用的。
The intrinsic reaction rates of methanol synthesis from CO-H_2 on the C_(301) copper-base catalyst was measured at 5 MPa by using the direct flow isothermal integral reactor. With the improved Newton-Gauss method, the parameter assessment were made for the intrinsic kinetics model of methanol synthesis of power function type and T-H-H -W type respectively, hence obtaining the kinetics equations. The experimental and calculated results showed that the two models were applicable.