文献类型：期刊文献

中文题名：An Efficient Palladium and Bis（2-pyridylmethyl）amine-based System for Suzuki-Miyaura Cross-Coupling under Aqueous and Aerobic Condition

英文题名：An Efficient Palladium and Bis(2-pyridylmethyl)amine-based System for Suzuki-Miyaura Cross-Coupling under Aqueous and Aerobic Condition

作者：Yu Jianjun;Wang Limin[1];Liu Mingtao;Qiu Jun;Shen Qiang;Fang Lei;Tang Jun

机构：[1]E China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2012

卷号：30

期号：5

起止页码：1114

中文期刊名：Chinese Journal of Chemistry

外文期刊名：CHINESE JOURNAL OF CHEMISTRY

收录：;Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000304045600018)，CCR-EXPANDED(收录号:WOS:000304045600018)】；CSCD:【CSCD2011_2012】；

基金：This work was financially supported by the National Natural Science Foundation of China (No. 20672035).

语种：英文

中文关键词：Suzuki-Miyaura cross-coupling;bis（2-pyridylmethyl）amine-based ligand;arylboronic acids;aryl halides

外文关键词：Suzuki-Miyaura cross-coupling; bis(2-pyridylmethyl)amine-based ligand; arylboronic acids; aryl halides

摘要：A novel PdC12/bis（2-pyridylmethyl）amine-based ligand （1） catalytic system, which is water-soluble and air-stable, has been successfully synthesized and applied for Suzuki-Miyaura cross-coupling reaction. In the presence of catalytic amount of PdCl2/1 system, arylboronic acids can couple with a wide range of aryl halides, including aryl bromides and aryl chlorides. The reactions proceed under mild conditions to give excellent yields, and a wide range of functionalities is tolerated.
A novel PdCl2/bis(2-pyridylmethyl)amine-based ligand (1) catalytic system, which is water-soluble and air-stable, has been successfully synthesized and applied for Suzuki-Miyaura cross-coupling reaction. In the presence of catalytic amount of PdCl2/1 system, arylboronic acids can couple with a wide range of aryl halides, including aryl bromides and aryl chlorides. The reactions proceed under mild conditions to give excellent yields, and a wide range of functionalities is tolerated.