文献类型：期刊文献

中文题名：基于聚薁胺的全固态超级电容器性能

英文题名：Properties of Poly(2-aminoazulene)-Based All-Solid-State Supercapacitors

作者：金欣[1,2];陈祉安[3];孙赛[1,4];庄小东[2];陈彧[1]

机构：[1]华东理工大学化学与分子工程学院,教育部结构可控先进功能材料及其制备重点实验室,上海200237;[2]上海交通大学化学化工学院,上海200240;[3]上海市第五十四中学,上海200030;[4]中国石油化工股份有限公司上海石油化工研究院,上海201208

年份：2021

卷号：34

期号：5

起止页码：418

中文期刊名：功能高分子学报

外文期刊名：Journal of Functional Polymers

收录：CSTPCD;;北大核心:【北大核心2020】；CSCD:【CSCD2021_2022】；

基金：国家自然科学基金(51961145402,51722304,51973114,51973061)。

语种：中文

中文关键词：薁;聚薁胺;导电聚合物;超级电容器

外文关键词：azulene;poly(2-aminoazulene);conductive polymer;supercapacitor

摘要：报道了一种新型导电聚合物聚薁胺,并制备了基于聚薁胺作为电极材料,磷酸/聚乙烯醇作为电解液的全固态超级电容器,研究了聚薁胺电容器的的基本性质。电化学测试结果表明,该器件在工作电压窗口?0.2~0.8 V下表现出优异的电容性能,可实现最大体积电容83 F/cm^(3)和最大的面积比电容0.54 mF/cm^(2),最大能量密度和最大功率密度分别为11.6 mW·h/cm^(3)和3304 W/cm^(3)。此外,该器件循环测试1000圈后仍保存初始电容的95.1%,表现出优异的循环稳定性。结果证明聚薁胺可以应用于超级电容器,为开发本征导电聚合物的探索提供了新策略。
Conductive polymers with good intrinsic conductivity and high charge density are considered as potential electrode materials for supercapacitors.However,it has been reported that the chains of polypyrrole and polyaniline could expand and contract during the charging and discharging process,leading to structural de-conformation.Poly(2-aminoazulene)is lately reported to present large area film morphology and remarkable electrical conductivity at room temperature.Nevertheless,relevant studies based on azulene as supercapacitor electrode materials have rarely been reported.Here,we report an all-solid-state supercapacitor based on a conductive polymer,poly(2-aminoazulene),as the electrode material.According to conventional electrochemical measurement,poly(2-aminoazulene)film-based device exhibits promising capacitive performance in the operating voltage window of?0.2—0.8 V:maximum volumetric capacitance of 83 F/cm^(3) and maximum areal capacitance of 0.54 mF/cm^(2),maximum energy density of 11.6 mW·h/cm^(3) and maximum power density of 3304 W/cm^(3).In addition,the supercapacitor retains 95.1%of the initial capacitance after 1000 cycles,indicating good cycling stability which enables its reliability during practical applications.These results not only prove that poly(2-aminoazulene)could be next generation candidates of all-solid-state supercapacitor electrode materials but also provide a new strategy for exploration of intrinsic conductive polymers for energy storage.