文献类型：期刊文献

英文题名：Vanadium oxide nanorods embed in porous graphene aerogel as high-efficiency polysulfide-trapping-conversion mediator for high performance lithium-sulfur batteries

作者：Zhang, Yongzheng[1];Ge, Xia[1];Kang, Qi[2];Kong, Zhenkai[1];Wang, Yanli[1];Zhan, Liang[1]

机构：[1]East China Univ Sci & Technol, State Key Lab Chem Engn, Key Lab Specially Funct Polymers & Related Techno, Minist Educ,Shanghai Key Lab Multiphase Mat Chem, Shanghai 200237, Peoples R China;[2]Shanghai Jiao Tong Univ, Dept Polymer Sci & Engn, Shanghai Key Lab Elect Insulat & Thermal Ageing, Shanghai 200240, Peoples R China

年份：2020

卷号：393

外文期刊名：CHEMICAL ENGINEERING JOURNAL

收录：;EI(收录号：20201108289857);WOS:【SCI-EXPANDED(收录号:WOS:000532784000018)】；

基金：This work was financially supported by National Science Foundation of China (51472086, 51002051, U1710252, 91834301). We also thank Dr. Hu Pengfei, who serves in the Instrumental Analysis and Research Center of Shanghai University, for his help in microstructural characterization and analysis of materials.

语种：英文

外文关键词：Functional separator; Shuttle effect; Electrocatalysis; Lithium-sulfur batteries

摘要：Lithium-sulfur (Li-S) batteries are highly desirable for next-generation energy storage and conversion systems because of their low cost, high energy density and unparalleled specific capacity. However, the sluggish redox kinetics and shuttling effect severely restrict the practical application of Li-S batteries. Herein, vanadium oxide nanorods were embedded in porous graphene aerogel (GA-VOx) as a dual-functional separator for the inhibition of shuttle effect and enhancement of conversion kinetic. The embedded VOx nanorods not only can chemisorb the lithium polysulfides (LiPSs) but also catalyze the LiPSs into short chain Li2S. Based on these merits, the cell with GA-VOx/CB functional separator exhibits good cycling performance (708 mAh g(-1) after 200 cycles at 0.2 C) and high rate performance (442 mAh g(-1) at 2 C) than that of CB functional separator. Additionally, even with a high sulfur loading of 2.6 mg cm(-2), the cell still delivers a stable specific capacity of 630 mAh g(-1) after 140 cycles at 0.2 C. This work provides a new route for practical application of Li-S batteries.