文献类型：期刊文献

中文题名：萘酰亚胺类共聚色素的合成

英文题名：Sduty on Copolymeric Colorant of Naphthlic Imide Derivatives

作者：严宏宾[1];沈永嘉[1];董黎芬[1]

机构：[1]华东理工大学精细化工研究所

年份：1997

卷号：10

期号：2

起止页码：195

中文期刊名：功能高分子学报

外文期刊名：Journal of Functional Polymers

收录：CSTPCD;;CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：荧光染料;聚合色素;甲基丙烯酸甲酯;自由基共聚

外文关键词：Fluorescent dyes, Polymeric colorant, Methyl-methacrylate, Free radical copolymerisation, 1H-benzisoquinolin-1,3(2H)-dione

摘要：以６－溴－１Ｈ，３Ｈ－萘并［１，８－ｃｄ］吡喃－１，３－二酮为原料，经亚胺化、Ｕｌｍａｍｎ缩合后与丙烯酰氯酯化得到具有荧光的可聚合单体６－（Ｎ－丙烯酰氧乙基）氨基－２－（２’，４’－Ｎ，Ｎ－二甲基）苯基－１Ｈ－苯并［ｄｅ］异喹啉－１，３（２Ｈ）－二酮，它与甲基丙烯酸甲酯经自由基共聚得到具有强烈荧光的聚合色素。
With 6-bromo-1H,3H-naphthopyran-1,3-dione as starting material, 6-(N-acryloxy-ethyl)amino-2-(2',4'-dimethyl)amino-1H-benzisoquinolin-1,3(2H)-dione was synthesized through imidation, Ulmamn condensation and esterification. The title copolymer, which showed intensive yellowish-green fluorescence, was then obtained through free radical copolymerisation. Its molecular weigh distribution, absorbing spectra and fluorescence spectra were measured.