文献类型：期刊文献

英文题名：N-heterocyclic carbene-acetylamide palladium complexes and their catalytic activities in Heck-Mizoroki reactions

作者：Zhang, Tao[1,2];Liu, Sijia[1,2];Shi, Min[1,2,3];Zhao, Meixin[1,2]

机构：[1]E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

年份：2008

期号：17

起止页码：2819

外文期刊名：SYNTHESIS-STUTTGART

收录：;EI(收录号：20083911594071);WOS:【SCI-EXPANDED(收录号:WOS:000259301000019)】；

基金：We thank the Shanghai Municipal Committee of Science and Technology (04JC14083, 06XD14005), the National Natural Science Foundation of China (20472096, 20672127, 20772030 and 20732008), and the Cheung Kong Scholar Program for financial support.

语种：英文

外文关键词：N-heterocyclic carbene-acetylamide; dinuclear NHC-Pd(II) complex; binaphthyl-2,2'-diamine; Heck-Mizoroki reaction

摘要：A novel N-heterocyclic carbene-acetylamide ligand derived from binaphthyl-2,2'-diamine (BINAM) and its dinuclear NHC-Pd(II) complex as well as its corresponding complex bearing weakly coordinating acetate counterions, have been successfully synthesized in good yields. The dinuclear NHC-Pd(II) complex has been characterized by X-ray diffraction. Moreover, we found that these complexes are quite effective in Heck-Mizoroki reactions and give the corresponding products in good to excellent yields.