文献类型：期刊文献

英文题名：Prussian blue and its analogues for aqueous energy storage: From fundamentals to advanced devices

作者：Jiang, Mingwei[1,2];Hou, Zhidong[1,2];Ren, Lingbo[1,2];Zhang, Yu[3];Wang, Jian-Gan[1,2]

机构：[1]Northwestern Polytech Univ, Ctr Nano Energy Mat, Sch Mat Sci & Engn, State Key Lab Solidificat Proc, Xi'an 710072, Peoples R China;[2]Shaanxi Joint Lab Graphene NPU, Xi'an 710072, Peoples R China;[3]East China Univ Sci & Technol, Sch Mech & Power Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China

年份：2022

卷号：50

起止页码：618

外文期刊名：ENERGY STORAGE MATERIALS

收录：;EI(收录号：20222412214313);WOS:【SCI-EXPANDED(收录号:WOS:000816985500001)】；

基金：Acknowledgments The work is supported by the National Natural Science Foundation of China (51772249, 22109044, and 51821091) , Fundamental Research Funds for the Central Universities (D5000210894 and 3102019JC005) . The authors also appreciate the TEM analysis from the Analytical & Testing Center of Northwestern Polytechnical University.

语种：英文

外文关键词：Prussian blue; Analogues; Aqueous energy storage; Working mechanism; Design strategies

摘要：Aqueous energy storage technologies promise grand advantages in the field of grid-scale power stations due to their attractive characteristics of low cost, safe operation, and environmental benignity. Nevertheless, the complex energy storage mechanism in aqueous media expresses rigid requirements for the host materials. As a kind of metal-organic coordination materials, Prussian blue (PB) and its analogues (PBAs) have been drawing immense research activities because of their open framework desirable for reversible insertion/extraction of various guest cations. In this review, the fundamental chemistry and electrochemistry of PB/PBAs are firstly discussed. Subsequent emphasis is put on the discussion of effective design strategies toward specific issues. Recent advances of PB/PBAs in different aqueous batteries and supercapacitors are then substantially scrutinized by correlating the electrochemical properties with the structural and compositional characteristics. To conclude, the ongoing challenges and critical perspectives for future development of PB/PBAs toward practical aqueous energy storage devices are provided.