文献类型：期刊文献

英文题名：Chloralkanes as chlorinating agents: An efficient approach to acyl chlorides and destruction of chlorinated hydrocarbons

作者：Chu, Changhu[1];Liu, Renhua[1]

机构：[1]E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

年份：2011

卷号：101

期号：3-4

起止页码：343

外文期刊名：APPLIED CATALYSIS B-ENVIRONMENTAL

收录：;EI(收录号：20105113512904);WOS:【SCI-EXPANDED(收录号:WOS:000287068400021)】；

基金：This work was supported by grants from the National High Technology Research and Development Program of China (863 Program) (No. 2008AA062306) and the National Natural Science Foundation of China (No. 21072055).

语种：英文

外文关键词：Carbon tetrachloride; Ferric chloride; Chlorination; Acyl chloride

摘要：Carbon tetrachloride, a low value and banned compound, was utilized to chlorinate organic acids in the presence of catalytic amount of FeCl3. A wide range of organic acids were smoothly transferred to corresponding acyl chlorides, while the carbon tetrachloride itself was consumed. Further more, some substituted benzoic acids which are not easy to be chlorinated by normal chlorination reagents are efficiently transferred to acyl chlorides by this chlorination method. (c) 2010 Elsevier B.V. All rights reserved.