文献类型：期刊文献

英文题名：Improvement of thermal conductivity and mechanical properties for polybenzoxazine composites via incorporation of epoxy resin and segregated structure

作者：Wang, Yi[1];Wu, Wei[1];Drummer, Dietmar[2];Liu, Chao[1];Tomiak, Florian[2];Schneider, Kevin[2]

机构：[1]East China Univ Sci & Technol, Sch Mat Sci & Engn, Sino German Joint Res Ctr Adv Mat, Shanghai 200237, Peoples R China;[2]Friedrich Alexander Univ Erlangen Nuremberg, Inst Polymer Technol, D-91058 Erlangen, Germany

年份：2020

卷号：7

期号：9

外文期刊名：MATERIALS RESEARCH EXPRESS

收录：;EI(收录号：20204209339304);WOS:【SCI-EXPANDED(收录号:WOS:000569748000001)】；

基金：This work was funded by the Chinese German Centre for the Promotion of Science via the National Natural Science Foundation of China (NSFC ) and Deutsche Forschungsgemeinschaft (DFG) under [grant number GZ1448].

语种：英文

外文关键词：thermal conductivity; segregated structure; polybenzoxazine; composites

摘要：Developing tendency of increasing integration in electronic components filed led to the demand for thermally conductive polymer materials. Forming a segregated structure with thermally conductive fillers in the matrix has been proven to be a promising technique. However, the mechanical properties of the material prepared via this technique are commonly sacrificed because the interaction between fillers and matrix are weak. We present a simple method to improve the mechanical properties while maintaining the segregated structure via the collaboration of epoxy and polybenzoxazine(PBz). The fillers, epoxy resin, and benzoxazine(BOZ) were mixed and then hot pressed under 12 MPa of pressure with a certain heating strategy. The thermal conductivity, density, mechanical properties, morphology, and thermal stability of the composites were investigated. With 25 wt% filler, the value of thermal conductivity coefficient of EP/PBz composites reached 0.811 W mK(-1), while that of PBz composites was 0.762 W mK(-1). The tensile strength of the matrix improved from 58.3 MPa to 99.7 MPa.