文献类型：期刊文献

英文题名：Hydrogen production from glycerol steam reforming over Ni/La/Co/Al2O3 catalyst

作者：Fu Ming[1];Xu Qingli[1];Qi Wei[2];Zhang Zhikai[1];Zhang Suping[1];Yan Yongjie[1]

机构：[1]East China Univ Sci & Technol, Minist Educ, Key Lab Coal Gasificat & Energy Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Guangzhou Energy Convers Inst, Guangzhou, Guangdong, Peoples R China

年份：2016

卷号：38

期号：14

起止页码：2128

外文期刊名：ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS

收录：;EI(收录号：20163202681161);WOS:【SCI-EXPANDED(收录号:WOS:000382363800020)】；

基金：This project was financially supported by the National Natural Science Foundation of China (No. 21006028, No. 21376084) and CAS Key Laboratory of Renewable Energy (No. y207kb1001).

语种：英文

外文关键词：Catalyst; glycerol; hydrogen; reforming; steam

摘要：Hydrogen production by steam reforming reaction of glycerol over Co/La/Ni-Al2O3 was studied in tubular fixed-bed reactor. The influences of operating parameters such as temperature, steam/carbon ratio, and weight hourly space velocity (WHSV) on hydrogen yield and carbon conversion were examined under atmospheric pressure. The results showed that carbon conversion increased with the increase of temperature and steam-to-carbon mole ratio (S/C). At 700 degrees C, S/C=3:1, and WHSV=2.5h(-1), hydrogen yield and potential hydrogen yield were up to 77.64% and 89.64%, respectively; meanwhile, the carbon conversion reached 96.36%.