文献类型：期刊文献

英文题名：Nickel-catalyzed methylation of aryl halides/tosylates with methyl tosylate

作者：Wang, Jiawang[1,2];Zhao, Jianhong[3];Gong, Hegui[1,2]

机构：[1]Shanghai Univ, Ctr Supramol Chem & Catalysis, 99 Shang Da Rd, Shanghai 200444, Peoples R China;[2]Shanghai Univ, Dept Chem, 99 Shang Da Rd, Shanghai 200444, Peoples R China;[3]East China Univ Sci & Technol, Sch Pharm, Lab Green Pharmaceut Proc & Technol, Shanghai 200237, Peoples R China

年份：2017

卷号：53

期号：73

起止页码：10180

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000410360700020)，CCR-EXPANDED(收录号:WOS:000410360700020)】；

基金：Financial support was provided by the Chinese NSF (No. 21372151 and 21572127), Shanghai Municipal Education Commission for the Peak Discipline Construction (N.13-A302-15-L02). We thank Dr Hongmei Deng (Shanghai Univ.) for the use of the NMR facility.

语种：英文

摘要：This work describes the cross-electrophile methylation of aryl bromides and aryl tosylates with methyl tosylate. The mild reaction conditions allow effective methylation of a wide set of heteroaryl electrophiles and dimethylation of dibromoarenes.