文献类型：期刊文献

英文题名：Solid-State Synthesis, Characterization, and Biological Activity of the Bioinorganic Complex of Aspartic Acid and Arsenic Triiodide

作者：Zhong, Guo-Qing[1];Zhong, Wen-Wei[2];Jia, Rong-Rong[3];Jia, Yu-Qing[3]

机构：[1]Southwest Univ Sci & Technol, State Key Lab Cultivat Base Nonmet Composite & Fu, Sch Mat Sci & Engn, Mianyang 621010, Peoples R China;[2]Sichuan Univ, Coll Life Sci, Chengdu 610064, Peoples R China;[3]E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China

年份：2013

卷号：2013

外文期刊名：JOURNAL OF CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000324176700001)】；

基金：This work is supported by the Scientific Research Funds of Sichuan Provincial Education Department (10ZA016) and Science and Technology Bureau of Sichuan Province in China (05JY029-113).

语种：英文

摘要：The bioinorganic complex of aspartic acid and arsenic triiodide was synthesized by a solid-state reaction at room temperature. The formula of the complex is AsI3[HOOCCH2CH(NH2)COOH](2.5). The crystal structure of the complex belongs to monoclinic system with lattice parameters: a = 1.0019 nm, b = 1.5118 nm, c = 2.1971 nm, and beta = 100.28 degrees. The infrared spectra can demonstrate the complex formation between the arsenic ion and aspartic acid, and the complex may be a dimer with bridge structure. The result of primary biological test indicates that the complex possesses better biological activity for the HL-60 cells of the leukemia than arsenic triiodide.