文献类型：期刊文献

英文题名：Selective synthesis of 1-O-alkyl glycerol and diglycerol ethers by reductive alkylation of alcohols

作者：Shi, Yan[1,2,3];Dayoub, Wissam[1];Chen, Guo-Rong[2,3];Lemaire, Marc[1]

机构：[1]Univ Lyon 1, CNRS, UMR5246, ICBMS,Lab Catalyse Synth & Environm, F-69622 Villeurbanne, France;[2]E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China;[3]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2010

卷号：12

期号：12

起止页码：2189

外文期刊名：GREEN CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000285682500017)】；

基金：Financial support allocated in the framework of the MIRA collaborative program between Region Rhone-Alpes and Shanghai City (P. R. China) is gratefully received. China Scholarship Council is also warmly thanked for PhD grants to S. Y.

语种：英文

摘要：1-O-alkyl glycerol and diglycerol ethers are obtained in high yields and high selectivity by catalytic reductive alkylation of glycerol and diglycerol with linear aldehydes in the presence of 0.5 mol% of Pd/C under 10 bars of hydrogen using a Bronsted acid as co-catalyst. All byproducts were identified. A mechanism for the reductive alkylation is proposed.