文献类型：期刊文献

英文题名：Direct arylation of tertiary amines via aryne intermediates using diaryliodonium salts

作者：Zhang, Zhiang[1];Wu, Xunshen[1];Han, Jianwei[1,2];Wu, Wenjun[1];Wang, Limin[1]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, 345 Ling Ling Rd, Shanghai 200032, Peoples R China

年份：2018

卷号：59

期号：18

起止页码：1737

外文期刊名：TETRAHEDRON LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000430778700012)，CCR-EXPANDED(收录号:WOS:000430778700012)】；

基金：The work was supported by National Key Program (2016YFA0200302, Study on application and preparation of aroma nanocomposites), the National Nature Science Foundation of China (NSFC 21472213, 21772039), and the Fundamental Research Funds for the Central Universities, Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

语种：英文

外文关键词：Diaryliodonium salts; Benzyne; Arylation; Aromatic tertiary amines

摘要：With a strategy by using diaryliodonium salts as the precursors of benzynes, direct N-arylation of tertiary amines with diaryliodonium salts was reported. Thus, the desired aromatic tertiary amines with a wide range of substituents were synthesized in moderate to excellent yields of 55-91%. (C) 2018 Elsevier Ltd. All rights reserved.