文献类型：期刊文献

英文题名：Cooperative catalysis for the direct hydrodeoxygenation of vegetable oils into diesel-range alkanes over Pd/NbOPO4

作者：Xia, Qineng[1,2];Zhuang, Xiaojing[2];Li, Molly Meng-Jung[1];Peng, Yung-Kang[1];Liu, Guoliang[1];Wu, Tai-Sing[3];Soo, Yun-Liang[3];Gong, Xue-Qing[2];Wang, Yanqin[2];Tsang, Shik Chi Edman[1]

机构：[1]Univ Oxford, Dept Chem, Wolfson Catalysis Ctr, Oxford OX1 3QR, England;[2]E China Univ Sci & Technol, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China;[3]Natl Tsing Hua Univ, Dept Phys, Hsinchu, Taiwan

年份：2016

卷号：52

期号：29

起止页码：5160

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000373629800018)】；

基金：The authors wish to thank EPSRC, UK, and National Synchrotron Radiation Research Center, Hsinchu, Taiwan (Prof. Soo), for access of EXAFS and are grateful to the CSC to grant studentships to QX and GL to work at Oxford.

语种：英文

摘要：Near quantitative carbon yields of diesel-range alkanes were achieved from the hydrodeoxygenation of triglycerides over Pd/NbOPO4 under mild conditions with no catalyst deactivation: catalyst characterization and theoretical calculations suggest that the high hydrodeoxygenation activity originated from the synergistic effect of Pd and strong Lewis acidity on the unique structure of NbOPO4.