文献类型：期刊文献

中文题名：过碱性重烷基苯磺酸钙清净剂烃基结构的研究

英文题名：STUDY ON ALKYL GROUP STRUCTURE OF OVERBASED CALCIUM ALKYL BENZENE SULFONATE

作者：张峥[1];韦刚[2];苏克曼[1];严正泽[1];翁惠新[1]

机构：[1]华东理工大学化工学院,上海210037;[2]上海海润添加剂有限公司,200137

年份：2002

卷号：19

期号：2

起止页码：19

中文期刊名：精细石油化工

外文期刊名：Speciality Petrochemicals

收录：CSTPCD;;Scopus;北大核心:【北大核心2000】；CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：过碱性重烷基苯磺酸钙;清净剂;烃基结构;研究;烷基苯磺酸钙;电子轰击质谱;电喷雾质谱;润滑油添加剂

外文关键词：calcium alkylbenzene sulfonate; detergent dispersant; alkyl group structure; EIMS; ESI MS

摘要：研究了过碱性重烷基苯磺酸钙清净剂的烃基结构 ,通过使用 EIMS(电子轰击质谱 )、ESI MS(电喷雾质谱 )、红外光谱等现代实验技术 ,直接测定经转化处理过的磺酸钙清净剂 ,得出其主要的烷基芳烃化学组成为单烷基苯和对位二烷基苯 ,含量占 42 % ;茚满、苯骈二环己烷类化合物、烷基萘和苊类化合物 ,含量约 47.7%。烷基芳烃部分的平均相对分子质量是 3 2
The alkyl group structure of overbased calcium alkyl benzene sulfonate has been studied by EIMS, ESIMS and IR spectra. The results showed that the main alkyl aromatics were consisted of monoalkyl benzene and para dialkyl benzene, their total content was ca. 42%. Other compounds such as indane, benzocyclohexane, alkylnaphthalene and acenaphthene dirivatives were also existed and their total content was ca. 47.7%. The average molecular weight of alkyl aromatic components was 322.