文献类型：期刊文献

英文题名：Chemically Bonding NiFe-LDH Nanosheets on rGO for Superior Lithium-Ion Capacitors

作者：Tian, Meng[1,2];Liu, Chaofeng[2];Neale, Zachary G.[2];Zheng, Jiqi[2];Long, Donghui[1,3];Cao, Guozhong[2]

机构：[1]East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;[2]Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA;[3]East China Univ Sci & Technol, Shanghai Key Lab Multiphase Mat Chem Engn, Shanghai 200237, Peoples R China

年份：2019

卷号：11

期号：39

起止页码：35977

外文期刊名：ACS APPLIED MATERIALS & INTERFACES

收录：;EI(收录号：20194107509376);WOS:【SCI-EXPANDED(收录号:WOS:000489001900052)】；

基金：This work was supported by the National Science Foundation (CBET-1803256), the National Science Foundation of China (No. 21576090), and the Fundamental Research Funds for the Central Universities (222201718002). Part of this work was conducted at the Molecular Analysis Facility, a National Nanotechnology Coordinated Infrastructure site at the University of Washington, which is supported, in part, by the National Science Foundation (grant NNCI-1542101), the University of Washington, the Molecular Engineering & Sciences Institute, and the Clean Energy Institute. M.T. and J.Z. acknowledge the financial support from CSC for this work at the University of Washington.

语种：英文

外文关键词：layered double hydroxide; highly dispersed nanosheets; reduced graphene oxide; high performance; lithium-ion storage

摘要：Layered double hydroxides (LDHs) have attracted tremendous interest for applications in energy harvest and storage. However, the aggregation of nanosheets compromises the accessible active sites and limits their electrochemical performance, especially at high rates. The present study reports the synthesis of highly dispersed NiFe-LDH nanosheets anchored on reduced graphene oxide (NiFe-LDH/rGO) composites chemically bonded via a facile one-step hydrothermal method. Defect-riched rGO provides abundant active sites for heterogeneous nucleation of NiFe-LDH nanosheets, achieving the much efficient charge transfer between rGO and NiFe-LDH as compared to physically mixed NiFe-LDH + rGO. The crystallite size can effectively reduce to 5.5 nm smaller than 15.1 nm of NiFe-LDH without rGO, beneficial to expose more active surface for fast ion diffusion and redox reactions. NiFe-LDH/rGO as an anode material in lithium-ion batteries shows superior lithium storage capacity with 1202 mAh g(-1) after 100 cycles at 100 mA g(-1) and high-rate performance with 543 mAh g(-1) even at 2000 mA g(-1). The corresponding lithium-ion capacitor with NiFe-LDH/rGO anode and mesoporous carbon microsphere cathode exhibits high energy density and power density simultaneously, with 133 Wh kg(-1) at 25 W kg(-1) and 4016 W kg(-1) at 58 Wh kg(-1), showing the great potential for high-performance hybrid energy storage systems.