文献类型：期刊文献

英文题名：Naphtho[2,3-b]furan-4,9-dione synthesis via palladium-catalyzed reverse hydrogenolysis

作者：Li, Jimei[1];Zhang, Jie[1];Li, Mingfei[1];Zhang, Chenyang[1];Yuan, Yongkun[2];Liu, Renhua[1]

机构：[1]East China Univ Sci & Technol, Sch Pharm, Meilong Rd 130, Shanghai 200237, Peoples R China;[2]Suzhou Yacoo Sci Co Ltd, Jinhai Rd 17,Suzhou Ind Pk, Suzhou 215125, Jiangsu, Peoples R China

年份：2019

卷号：55

期号：16

起止页码：2348

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000459022300021)】；

语种：英文

摘要：A reverse hydrogenolysis process has been developed for two-site coupling of 2-hydroxy-1,4-naphthoquinones with olefins to produce naphtha[2,3-b] furan-4,9-diones and hydrogen ( H2). The reaction is catalyzed by commercially available Pd/C without oxidants and hydrogen acceptors, thereby providing an intrinsically waste-free approach for the synthesis of functionalized and potentially biologically relevant naphtha[2,3-b] furan-4,9-diones.