文献类型：期刊文献

英文题名：Highly Active and Stable Co₃O₄/ZSM-5 Catalyst for Propane Oxidation: Effect of the Preparation Method

作者：Zhu, Zengzan;Lu, Guanzhong[1];Zhang, Zhigang;Guo, Yun;Guo, Yanglong;Wang, Yanqin

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

年份：2013

卷号：3

期号：6

起止页码：1154

外文期刊名：ACS CATALYSIS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000320298800010)】；

基金：We would like to acknowledge financial support from the National Basic Research Program of China (2010CB732300, 2013CB933201), the National Natural Science Foundation of China (21273150), the Fundamental Research Funds for the Central Universities, the National High Technology Research and Development Program of China (2012AA062703), and the "Shu Guang" Project (10GG23) of the Shanghai Municipal Education Commission and Shanghai Education Development Foundation.

语种：英文

外文关键词：Co3O4/ZSM-5; propane oxidation; catalyst preparation; high stability; high activity

摘要：Co3O4 supported on ZSM-5 (Co3O4/ZSM-5) catalysts were prepared by impregnation (IM), deposition precipitation (DP), and hydrothermal (HT) methods. Their catalytic performances for the total oxidation of propane were tested, and their physicochemical properties were investigated by low-temperature N-2 adsorption, XRD, FT-IR absorption spectroscopy, XPS, H-2-TPR, TEM, and CO chemisorption. The results show that the catalytic activity of Co3O4/ZSM-5 for propane oxidation is higher than that of 1.5 wt % Pd/ZSM-5, and the preparation methods remarkably affect the catalytic activity of Co3O4/ZSM-5. Among four Co3O4/ZSM-5 catalysts prepared by different methods, the catalyst prepared by the HT method possesses the highest catalytic activity for propane Oxidation, and their catalytic activities are varied in the order of HT > DP > IM. For the Co3O4/ZSM-5 (DP) catalysts, the precipitant has an evident influence On their catalytic activities. For instance, the DP catalyst prepared with ammonium bicarbonate precipitant has a higher catalytic activity than the catalyst prepared with,sodium hydroxide precipitant. The excellent catalytic activity of Co3O4/ZSM-5 (HT) may be attributed to the better reducibility of Co3+, higher Co3+ content, higher surface concentration, and fast migration of the lattice oxygen of Co3O4 On this catalyst. Furthermore, the Co3O4/ZSM-5 catalyst prepared by the HT method exhibits a high stability after being used at 500 degrees C for 40 h.