文献类型：期刊文献

英文题名：Unprecedentedly targeted customization of molecular energy levels with auxiliary-groups in organic solar cell sensitizers

作者：Xie, Yongshu[1]; Wu, Wenjun[1]; Zhu, Haibo[1]; Liu, Jingchuan[1]; Zhang, Weiwei[1]; Tian, He[1]; Zhu, Wei-Hong[1]

机构：[1] Key Laboratory for Advanced Materials, Institute of Fine Chemicals, Shanghai Key Laboratory of Functional Materials Chemistry, Collaborative Innovation Center for Coal Based Energy [I-CCE], East China University of Science and Technology, Shanghai, 200237, China

年份：2015

卷号：7

期号：1

起止页码：544

外文期刊名：Chemical Science

收录：EI(收录号：20155201711846)

语种：英文

外文关键词：Photoelectricity - Dye-sensitized solar cells - Electrons

摘要：In dye-sensitized solar cells (DSSCs), the HOMO-LUMO energy gap of organic sensitizers should be large enough to enable efficient electron injection and dye regeneration. However, the LUMOs of most practical organic dyes are always too high, making energy "waste". In order to deepen the LUMOs, we focus on the targeted modulation of the molecular energy levels by embedding an electron donor or acceptor into the skeleton of a typical D-π-A model. The electron-rich group of 3,4-ethylenedioxythiophene (EDOT) lifts up the HOMO level with little influence on the LUMO, while the electron-deficient group of benzothiadiazole (BTD) or benzooxadiazole (BOD) mainly lowers the customized LUMO level. As a consequence, the auxiliary group change from EDOT (dye WS-53) to BOD (dye WS-55) brings forth a huge photoelectric conversion efficiency (PCE) increase by 38 fold from 0.24 to 9.46% based on an I-/I3- redox couple, and even reaching a high PCE of 10.14% with WS-55 under 0.3 sunlight irradiation. ? The Royal Society of Chemistry.