文献类型：期刊文献

中文题名：亲电取代反应中相转移催化剂结构和性能的关系

英文题名：Studies of Phase Transfer Catalysis in the Electrophilic Substitution──Relation between the Catalytic Power and the Structure

作者：罗海航[1];祁国珍[1];王金娣[1]

机构：[1]华东理工大学精细化工系,华东理工大学精细化工研究所

年份：1996

卷号：22

期号：2

起止页码：153

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;国家哲学社会科学学术期刊数据库;Scopus;CSCD:【CSCD2011_2012】；

基金：国家自然科学基金

语种：中文

中文关键词：亲电取代;相转移催化;偶合反应;催化剂

外文关键词：electrophilic substitution;phase transfer catalysis; catalytic power;structure;kinetic;coupling reaction

摘要：选择了１０个含磺酸基团的化合物作为相转移催化剂，测定其在Ｈ_２Ｏ／ＣＨ_２ＣＯＯＨ－ＣＨ_３ＣＯＯＮａ／ＣｌＣＨ_２Ｃｌ体系中的亲电偶合反应速率常数。对比无催化剂存在时的动力学数据，证明这类化合物是有效的亲电取代反应的相转移催化剂。通过动力学数据测定，证明催化性能与催化剂及离子对结构中的亲水、亲油基团存在着定量关系。
Ten sulfo-group containing compound were tested whether they could be used as the phase transfer catalyst (PT CS) for the electrophilic substitution in the solution of H2O/CH3COONa-CH3COOH/ClCH2Cl by measuring the coupling reaction rate constant.When compared with the kinetic data of the reaction without PTCS,these compounds proved to be effective catalysts for the electrophilic reaction.According to the kinetic investigation,their catalytic power is quantitatively related to the presence of the hydrophilic and oleophilicgroup in the structure of the catalyst and the ion pair.