文献类型：期刊文献

中文题名：全氟丁基取代烯烃的制备及其硼氢化反应

英文题名：The Preparation and Hydrobration Reaction of Perfluorobutyl Substituted Alkenes

作者：荣国斌[1]

机构：[1]华东理工大学化学系,上海200237

年份：1995

卷号：15

期号：4

起止页码：370

中文期刊名：有机化学

外文期刊名：Chinese Journal of Organic Chemistry

收录：CSTPCD;;Scopus;北大核心:【北大核心1992】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：全氟丁基;取代烯烃;硼氢化反应;合成

外文关键词：perfluorobutyl substituted olefins, hydroboration reaction, synthesis

摘要：在相转移催化或超声作用下,全氟丁基碘和烯烃或炔烃发生加成反应,从加成得到的烷烃脱碘化氢或烯烃加成产物脱碘还原生成全氟丁基取代烯烃。全氟丁基取代烯烃的硼氢化反应主要得到α-全氟丁基取代的硼烷。
Addition of perfluorobutyl iodide to C-C multiple bond is efficiently achieved by Na2S2O4 in phase transfer of ultrasonic irradiation condition. The perfluorobutyl alkenes are produced from the β-iodoperfluorobutyl alkanes by elimination of hydrogen iodide or from β-iodoperfluorobutyl alkenes by deiodoreduction. The hydroboration reaction of perfluorobutyl alkenes were also studied.