文献类型：期刊文献

英文题名：Production of biomass-derived monomers through catalytic conversion of furfural and hydroxymethylfurfural

作者：Yang, Zhirong[1];Zhang, Jing[1];Qian, Gang[1];Duan, Xuezhi[1];Zhou, Xinggui[1]

机构：[1]East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2021

卷号：2

期号：2

起止页码：158

外文期刊名：GREEN CHEMICAL ENGINEERING

收录：EI(收录号：20224313011771);WOS:【ESCI(收录号:WOS:001072929400001)】；

基金：This work was supported by the National Natural Science Foundation of China (22008074, 22008072, 21991103) ; Natural Science Foundation of Shanghai (20ZR1415700) , China Postdoctoral Science Foundation (2020M671025, 2019TQ0093) .

语种：英文

外文关键词：Biomass-derived monomers; Catalyst design; Furfural; Hydroxymethylfurfural; Heterogeneous catalysis

摘要：The synthesis of biomass-derived monomers has received great attention in recent years, motivated by the depletion of fossil fuels and environmental issues. Moreover, the intrinsic functionality within the biomass or biomass-derived chemicals has great potential to produce new types of monomers containing multiple acid or alcohol groups, thereby leading to materials with novel properties. Given their versatile functional groups and easy production from cellulose/hemicellulose, furfural and hydroxymethylfurfural were regarded as very important biomass-derived platform chemicals through which multiple monomers can be produced via heterogeneous catalysis. In the current review, recent development in heterogeneous catalysis for the production of 6 bio-based monomers, furfuryl alcohol, 2,5-bis(hydroxymethyl)furan, 2,5-bis-(hydroxymethyl)tetrahydrofuran, 1,5-pentanediol, 1,6-hexanediol, and 2,5-furandicarboxylic acid, from furfural and hydroxymethylfurfural is reviewed and summarized. The major challenge is how to efficiently and selectively convert specific functional group(s) in furfural and hydroxymethylfurfural during the production of these monomers. Additionally, catalyst stability issues need to be addressed due to necessity of using hot water as reaction medium and high tendency of carbonaceous deposit formation on catalyst surface. The current review mainly focuses on efforts of catalytic site design and modification, including selection of metal/support, use of synergy between metal and support, tuning metal size, use of inverse catalysts, adding catalytic promoters, constructing bimetallic sites, etc., to realize efficient, selective and stable production of bio-based monomers from furfural and hydroxymethylfurfural.