文献类型：期刊文献

英文题名：Induced Crystallization-Controllable Nanoarchitectonics of 3D-Ordered Hierarchical Macroporous Co@N-Doped Carbon Frameworks for Enhanced Microwave Absorption

作者：He, Peng[1];Ma, Wenjun[1];Xu, Jian[1];Wei, Jie[1];Liu, Xiaoyun[1];Zuo, Peiyuan[1];Cui, Zhong-Kai[2];Zhuang, Qixin[1]

机构：[1]East China Univ Sci & Technol, Sch Mat Sci & Engn, Key Lab Adv Polymer Mat Shanghai, Shanghai 200237, Peoples R China;[2]Southern Med Univ, Sch Basic Med Sci, Guangzhou 510515, Peoples R China

年份：2023

卷号：19

期号：1

外文期刊名：SMALL

收录：;EI(收录号：20224713133546);WOS:【SCI-EXPANDED(收录号:WOS:000880716600001)】；

基金：This work was supported by the National Natural Science Foundation of China (52073091, 22171086), Natural Science Foundation of Shanghai (20ZR1414600).

语种：英文

外文关键词：3D-ordered macroporous; impedance matching; microwave absorption; metal-organic frameworks (MOFs) derivatives

摘要：The construction of ordered hierarchical porous structures in metal-organic frameworks (MOFs) and their derivatives is highly promising to meet the low-density and high-performance demands of microwave absorption materials. However, traditional methods based on sacrificial templates or corrosive agents inevitably suffer from the collapse of the microporous framework and the accumulation of nanoparticles during the carbonization transformation, resulting in the deteriorating impedance match, which greatly limits the incident and attenuation of microwaves. Herein, an induced crystallization and controllable nanoarchitectonics strategy is employed to replace traditional growing-etching methods and successfully synthesize carbonized 3D-ordered macroporous Co@N-doped carbon (3DOM Co@NDC) based on the 3D-ordered template. The obtained 3D-ordered macroporous structure ensures the stable growth of hybrid carbon frameworks and Co-C nanoparticles without collapse, preserves abundant interfaces for both the incident and attenuation performance, so as to significantly improve the impedance matching and absorption properties compared to conventional MOFs derivatives. The minimum reflection loss of 3DOM Co@NDC is -57.36 dB at the thickness of 1.9 mm, and the effective bandwidth is 7.36 GHz at 1.6 mm. Moreover, the innovative strategy to prepare 3D-ordered hierarchical macroporous structures opens up a new avenue for advanced MOFs-derived absorbers with excellent performance.