文献类型：期刊文献

英文题名：Determination of the Interaction Enthalpy between Microemulsion Droplets by Isothermal Titration Microcalorimetry

作者：Zheng, Peizhu[1];Ma, Yuanming[2];Peng, Xuhong[2];Yin, Tianxiang[1];An, Xueqin[1];Shen, Weiguo[1,2]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[2]Lanzhou Univ, Dept Chem, Lanzhou 730000, Gansu, Peoples R China

年份：2011

卷号：27

期号：20

起止页码：12280

外文期刊名：LANGMUIR

收录：;EI(收录号：20114214429997);WOS:【SCI-EXPANDED(收录号:WOS:000295665400004)】；

基金：This work was supported by the National Natural Science Foundation of China (projects 20973061, 21073063 and 21173080) and the Committee of Science and Technology of Shanghai (08jc1408100).

语种：英文

外文关键词：Isotherms - Light scattering - Calorimeters - Enthalpy - Microemulsions - Titration

摘要：A new experimental design for the measurement of the real heat of dilution of the microemulsion droplets by isothermal titration microcalorimetry (ITC) has been reported and used to study the interaction enthalpies of the droplets for the system of water/sodium bis(2-ethylhexyl)-sulfosuccinate (AOT)/toluene. The results are in good agreement with those determined from light-scattering experiments.