文献类型：期刊文献

英文题名：Carbene transfer reactions enabled by heterogeneous metal catalysis

作者：Lu, Luan;Zhao, Jie[1]

机构：[1]East China Univ Sci & Technol, Feringa Nobel Prize Scientist Joint Res Ctr, Frontiers Sci Ctr Materiobiol & Dynam Chem, Sch Chem & Mol Engn,Key Lab Adv Mat, Shanghai 200237, Peoples R China; East China Univ Sci & Technol, Feringa Nobel Prize Scientist Joint Res Ctr, Frontiers Sci Ctr Materiobiol & Dynam Chem, Sch Chem & Mol Engn,Joint Int Res Lab Precis Chem, Shanghai 200237, Peoples R China

年份：2026

卷号：62

期号：2

起止页码：389

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;EI(收录号：20254819586728);WOS:【SCI-EXPANDED(收录号:WOS:001620724400001)】；

基金：J. Z. thanks The National Natural Science Foundation of China (22572050, 22301076) for funding support.

语种：英文

外文关键词：Carbon - Catalyst selectivity - Organic carbon - Synthesis (chemical)

摘要：Carbene transfer reactions are powerful tools for constructing both carbon-carbon and carbon-heteroatom bonds in organic synthesis. While homogeneous catalysts have achieved remarkable success in diverse transformations such as cyclopropanation and X-H insertion, heterogeneous systems offer distinct advantages, including enhanced recyclability, stability, and tuneable selectivity. This review summarizes recent advances in heterogeneous transition-metal-catalyzed carbene transformations, with particular emphasis on catalyst design, mechanistic insights, and synthetic applications.