文献类型：期刊文献

英文题名：Effect of viscoelasticity on the foaming behaviour of long-chain branched polypropylene with different branching degrees analysed by using bubble-growth modelling

作者：Song, Mingzhang[1]; Luo, Wei[2]; Feng, Shuibin[2]; Jiang, Wenjun[3]; Ge, Yukai[1]; Liu, Tao[1]

机构：[1] Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China; [2] Maoming Branch Co., SINOPEC, Maoming, Guangdong, China; [3] State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005, China

年份：2022

卷号：238

外文期刊名：Polymer

收录：EI(收录号：20214811252546)

语种：英文

外文关键词：Grafting (chemical) - Expansion - Size exclusion chromatography - Viscosity measurement - Viscoelasticity - Viscosity - Molecular mass - Coalescence - Styrene

摘要：Long-chain branched polypropylene (LCB-PP) was generated by a melt grafting reaction with trimethylolpropane triacrylate (TMPTA) as the grafting monomer and zinc dimethyldithiocarbamate (ZDMC) or styrene (St) as the co-monomers. High-temperature size exclusion chromatography (HT-SEC) was used to characterize the molecular mass, molecular mass distribution and branching degree of the modified PP. Subsequently, linear and nonlinear viscoelasticity data were obtained by a small amplitude oscillatory shear (SAOS) test and uniaxial extensional viscosity measurement. The pressure balanced bubble-growth (PBB) model was used to calculate the critical coalescence radius (CCR) curves for PP to quantitatively correlate the viscoelasticity and foamability and evaluate the foamability of PP combined with batch foaming. It is shown that with increasing branching degree, the foam shows a better resistance to bubble coalescence, resulting in a more regular bubble structure and a higher expansion ratio. Moreover, viscosity should be controlled over an appropriate range for realising good foamability; otherwise, excessive viscosity can suppress bubble growth and limit the expansion ratio. MPPZ4 modified with 4 wt% TMPTA and 0.4 wt% ZDMC showed the best foamability. A combination of the PBB model and batch foaming experiment is used to quantitatively explain the contribution of LCB to foaming. ? 2021 Elsevier Ltd