文献类型：期刊文献

英文题名：Simultaneous detection of trace metal ions in water by solid phase extraction spectroscopy combined with multivariate calibration

作者：Wang, Lei[1,2];Cao, Peng[3];Li, Wei[1,2];Tong, Peijin[1,2];Zhang, Xiaofang[1,2];Du, Yiping[1,2]

机构：[1]E China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Meilong Rd 130, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Res Ctr Anal & Test, Meilong Rd 130, Shanghai 200237, Peoples R China;[3]Yantai Entry Exit Inspect & Quarantine Bur, Beima Rd 66, Yantai 264000, Peoples R China

年份：2016

卷号：159

起止页码：151

外文期刊名：SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

收录：;EI(收录号：20160501881286);WOS:【SCI-EXPANDED(收录号:WOS:000372382500024)】；

基金：This work was supported by General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China (2015IK201) and Science and Technology Commission of Shanghai Municipality (14142201400).

语种：英文

外文关键词：SPES; UV-Visible spectroscopy; Membrane filtration; 1-(2-Pyridylazo)-2-naphthol(PAN); Simultaneous detection

摘要：Solid Phase Extraction Spectroscopy (SPES) developed in this paper is a technique to measure spectrum directly on the solid phase material where the analytes are concentrated in SPE process. Membrane enrichment and UV-Visible spectroscopy were utilized to fulfill SPES, and multivariate calibration method of partial least squares (PLS) was used to simultaneously detect the concentrations of trace cobalt (II) and zinc (II) in water samples. The proposed method is simple, sensitive and selective. The complexes of analyte ions were collected on the cellulose acetate membranes via membrane filtration after the complexation reaction with 1-2-pyridylazo 2 naphthol (PAN). The spectra of the membranes which contained the complexes of metal ions and PAN were measured directly without eluting. The analytical conditions including pH, reaction time, sample volume, the amount of PAN, and flow rates were optimized. Nonionic surfactant Brij-30 was absorbed on the membranes prior to SPES to modify the membranes for improving the enrichment and spectrum measurement. The interference from other ions to the determination was investigated. Under the optimal condition, the absorbance was linearly related to the concentration at the range of 0.1-3.0 mu g/L and 0.1-2.0 mu g/L, with the correlation coefficients (R-2) of 0.9977 and 0.9951 for Co (II) and Zn (II), respectively. The limits of detection were 0.066 mu g/L for cobalt (II) and 0.104 mu g/L for zinc (II). PLS regression with leave-one-out cross-validation was utilized to build models to detect cobalt (II) and zinc (II) in drinking water samples simultaneously. The correlation coefficient between ion concentration and spectrum of calibration set and independent prediction set were 1.0000 and 0.9974 for cobalt (II) and 1.0000 and 0.9956 for zinc (II). For cobalt (II) and zinc (II), the errors of the prediction set were in the range 0.0406-0.1353 mu g/L and 0.0025-0.1884 mu g/L. (C) 2016 Elsevier B.V. All rights reserved.