详细信息
氢化丁腈橡胶/受阻酚阻尼复合材料的制备与结构
Preparation and Structure of Hydrogenated Nitrile-Butadiene Rubber/Hindered Phenol Damping Composite
文献类型:期刊文献
中文题名:氢化丁腈橡胶/受阻酚阻尼复合材料的制备与结构
英文题名:Preparation and Structure of Hydrogenated Nitrile-Butadiene Rubber/Hindered Phenol Damping Composite
作者:曹元一[1];李聪[1];许海燕[1];牟海艳[1];吴驰飞[1]
机构:[1]华东理工大学材料科学与工程学院,高分子合金研究室,上海200237
年份:2009
卷号:35
期号:3
起止页码:385
中文期刊名:华东理工大学学报(自然科学版)
外文期刊名:Journal of East China University of Science and Technology
收录:CSTPCD;;Scopus;北大核心:【北大核心2008】;CSCD:【CSCD2011_2012】;
基金:国家自然科学基金(20674018)
语种:中文
中文关键词:氢化丁腈橡胶;受阻酚;阻尼;氢键;杂化
外文关键词:hydrogenated nitrile-butadiene rubber; hindered phenol; damping; hydrogen bonds hybrid
摘要:将受阻酚AO-80加入氢化丁腈橡胶(HNBR)中,成功制备了氢化丁腈橡胶/受阻酚阻尼复合材料。利用差示扫描量热分析(DSC)、X射线衍射分析(XRD)、动态力学分析(DMA)、扫描电子显微镜(SEM)等测试手段对该复合材料进行了表征。测试结果表明:随着AO-80含量的增加,复合材料的阻尼因子逐渐增大,峰值对应温度逐渐移动至室温附近;在氢化丁腈橡胶(HNBR)内部,AO-80以无定形微球颗粒和无定形聚集体两种形式存在,以这两种形式存在的AO-80均可以利用氢键作用提高HNBR的阻尼性能。
A hydrogenated nitrile-butadiene rubber(HNBR)/hindered phenol composite was successfully prepared by adding 3, 9-bis { 1, 1-dimethyl-2[β-(3-tert-butyl-4-hydroxy-5-methylphenyl) propionyloxy] ethyl}-2, 4, 8, 10-tetraoxaspiro [5,5]-undecane (AO-80) into HNBR. The microstructure of the HNBR/AO-80 composite was characterized by DSC, XRD, DMA and SEM. The results show that with the increasing of AO-80 amount, the loss tangent of composite gradually increases and the corresponding peak temperature shifts to higher temperature. In the HNBR matrix, AO-80 exists in the forms of vitrified microballoon particles and vitrified aggregates, both of which are capable of improving damping properties of HNBR by interaction of hydrogen bonds.
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