文献类型：期刊文献

中文题名：仿生模拟催化在新能源与CO_2光催化还原方面的研究及应用

英文题名：Bioinspired Catalysis for New Energy Exploration and CO_2 Photoreduction

作者：刘蕾[1];刘劲刚[1]

机构：[1]华东理工大学化学系,上海200237

年份：2013

卷号：25

期号：4

起止页码：563

中文期刊名：化学进展

外文期刊名：Progress in Chemistry

收录：CSTPCD;;Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000318131600015)】；北大核心:【北大核心2011】；CSCD:【CSCD2013_2014】；

基金：国家自然科学基金项目(No.21271072)资助

语种：中文

中文关键词：仿生催化;人工光合成;过渡金属配合物;新能源;光解水CO2光还原

外文关键词：bioinspired catalysis; artificial photosynthesis; transition metal complexes; new energy; watersplitting; CO2 photo-reduction

摘要：人工光合成是受到植物光合作用启发而兴起的前沿科研领域,对于新型能源的探索具有重要的研究价值。本文首先从植物光合作用的原理和关键化学过程出发,介绍了人工光合成体系的构建原则与方法,着重阐述了过渡金属配合物光催化剂在人工光合成各半反应(水的光催化氧化分解与CO2的还原转换)中的应用。其次,分析整理了近期国内外重点研究的过渡金属配合物光催化剂的种类,评价了各类过渡金属配合物光催化剂的结构特征及由其组成的不同光催化体系的特点和催化性能的差别,讨论了部分光催化剂的催化机理及优化其催化性能的方法。最后,展望了过渡金属配合物光催化剂在人工光合成领域的研究前景及发展方向。
Inspired by natural photosynthesis, artificial photosynthesis using solar energy and abundant natural resources, H20 and C02, to produce renewable energy fuels has recently been received considerable attentions. This review focuses on recent developments in construction of artificial photosynthesis systems. Special attention has been paid to the various kinds of transition metal complexes as photocatalysts employed in water oxidation as well as in CO2 photo-reduction reactions, the semi-reactions of artificial photosynthesis. The performances of various photocatalytic systems together with their related photocatalytic reaction mechanisms have been summarized and compared. The challenges of current studies and prospects for future development in artificial photosynthesis have also been suggested.