文献类型：期刊文献

英文题名：[RuH2(PPh3)4]-catalyzed michael addition reaction of α-fluoronitroalkanes

作者：Wang, Qi[1]; Chen, Qing-Yun[2]; Yang, Xianjin[1]; Guo, Yong[2]

机构：[1] Key Laboratory for Advanced Materials, Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China; [2] Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China

年份：2012

卷号：44

期号：24

起止页码：3815

外文期刊名：Synthesis (Germany)

收录：EI(收录号：20125115809722)

语种：英文

外文关键词：Ruthenium - Catalysis - Activation analysis - Carbon - Addition reactions

摘要：The Michael addition reactions of α-fluoronitroalkanes with various electron-deficient olefins were realized by catalysis of low-valence ruthenium species through Csp3-H activation, providing a useful way to construct a fluorinated quaternary carbon center. The reactions were carried out under neutral conditions, affording the desired products in moderate to excellent yields. ? Georg Thieme Verlag KG · Stuttgart · New York.