文献类型：期刊文献

英文题名：In-situ growth of hollow NiCo layered double hydroxide on carbon substrate for flexible supercapacitor

作者：Xuan, Xiaoyang[1];Qian, Min[1];Han, Lu[2];Wan, Lijia[2];Li, Yuquan[2];Lu, Ting[2];Pan, Likun[2];Niu, Yueping[1,3];Gong, Shangqing[1,3]

机构：[1]East China Univ Sci & Technol, Sch Sci, Dept Phys, Shanghai 200237, Peoples R China;[2]East China Normal Univ, Sch Phys & Mat, Shanghai Key Lab Magnet Resonance, Shanghai 200062, Peoples R China;[3]East China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai Engn Res Ctr Hierarch Nanomat, Key Lab Ultrafine Mat,Minist Educ, Shanghai 200237, Peoples R China

年份：2019

卷号：321

外文期刊名：ELECTROCHIMICA ACTA

收录：;EI(收录号：20193407353663);WOS:【SCI-EXPANDED(收录号:WOS:000485837700061)】；

基金：This work is sponsored by National Natural Science Foundation of China (Grant No. 61804054), Natural Science Foundation of Shanghai (18ZR1410400), Shanghai Sailing Program (17YF1403300), the Fundamental Research Funds for the Central Universities (Project No. 222201714017), and the Social Development Program of Shanghai (17DZ1200900, 18DZ2252400).

语种：英文

外文关键词：Hollow structure; NiCo LDH; Flexible supercapacitor

摘要：Layered double hydroxides (LDHs) have shown remarkable potentials in supercapacitors for their highly-redox capacitance. However, the poor contact with substrate, slow charge transfer and ion diffusion, and low electrical conductivity limit their capacitor performance. In this work, a flexible free-standing supercapacitor was designed, with in-situ grown hollow-structured NiCo layered double hydroxide (H-NiCo LDH) as the active material based on a partial Ni ion substitution of Co ion in ZIF-67, and flexible carbon material as the substrate. Systematical investigation has been conducted in terms of nano-structures of the active material NiCo LDH (hollow or laminar structure) and flexible carbon substrates (acidified carbon cloth or acidified carbon fibers). A hollow-structured NiCo LDH@acidified carbon cloth (H-NiCo LDH@ACC) sample showed a promising capacity of 1377 mC/cm(2)(3060 mF/cm(2)) at 1 mA/cm(2) , a low charge transfer resistance of 0.15 Omega, a capacity retention of 70% and a coulombic efficiency retention of 99% upon 10,000 cycles at 80 mA/cm(2). PDMS-sealed solid-state H-NiCo LDH@ACC//AC devices were fabricated with an energy density of 0.0708 mWh/cm(2) at a power density of 0.7 mW/cm(2), with no obvious capacity decrease upon bending angles from 0 degrees to 180 degrees. SEM, EDS, XPS, and XRD analyses indicated the H-NiCo LDH has been in-situ grown on flexible carbon substrates. Hollow-structured LDH accelerated charge transfer and ion diffusion compared with a laminar-structured LDH. Acidified carbon cloth (ACC) showed better electrical conductivity compared with the biomass-derived acidified carbon fibers. Thus, a H-NiCo LDH@ACC is proposed as a promising candidate of a flexible supercapacitor. (C) 2019 Elsevier Ltd. All rights reserved.