文献类型：期刊文献

英文题名：tert-Butoxide mediated cascade desulfonylation/arylation/hydrolysis of cyclic sulfonyimines using diaryliodonium salts: synthesis of diaryl ether derivatives bearing a 2-aldehyde group

作者：Qian, Xiaofei[1,2];Han, Jianwei[1,2,3];Wang, Limin[1,2]

机构：[1]East China Univ Sci & Technol, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Inst Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, 345 Ling Ling Rd, Shanghai 200237, Peoples R China

年份：2016

卷号：6

期号：92

起止页码：89234

外文期刊名：RSC ADVANCES

收录：;EI(收录号：20163902857093);WOS:【SCI-EXPANDED(收录号:WOS:000384441200039)】；

基金：This work was supported by grants from the National Nature Science Foundation of China (NSFC No. 21272069, 21472213, 21202186) and the Fundamental Research Funds for the Central Universities, Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

语种：英文

外文关键词：Ethers

摘要：Cascades of cyclic sulfonyimines mediated by (BuOK)-Bu-t with diaryliodonium salts has been developed, giving the diaryl ethers in good yields. Furthermore, bulky ortho-substituted diaryl ethers with an aldehyde group can be obtained easily in comparision with metal-catalyzed protocols.