文献类型：期刊文献

英文题名：Synthetic porphyrin chemistry in China

作者：Li, Chengjie[1,2];Zhang, Junlong[3];Song, Jianxin[4];Xie, Yongshu[1,2];Jiang, Jianzhuang[5]

机构：[1]East China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Sch Chem & Mol Engn, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China;[4]Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Key Lab Applicat & Assemble Organ Funct Mol, Minist Educ China, Changsha 410081, Hunan, Peoples R China;[5]Univ Sci & Technol Beijing, Dept Chem, Beijing Key Lab Sci & Applicat Funct Mol & Crysta, Beijing 100083, Peoples R China

年份：2018

卷号：61

期号：5

起止页码：511

外文期刊名：SCIENCE CHINA-CHEMISTRY

收录：;EI(收录号：20181304941615);WOS:【SCI-EXPANDED(收录号:WOS:000431179300004)】；

基金：This work was supported by the National Natural Science Foundation of China (21472047, 21772041, 21702062), the Program for Professor of Special Appointment (Eastern Scholar, GZ2016006) at Shanghai Institutions of Higher Learning, Shanghai Pujiang Program (17PJ1401700), and the Fundamental Research Funds for the Central Universities (WK1616004, 222201717003, 222201714013).

语种：英文

外文关键词：Condensation reactions - Condensation - Cyclization

摘要：Porphyrins are a class of heterocyclic macrocycles, containing four pyrrolic subunits interconnected at the α-positions with four methine groups. In the early time, the lack of modern techniques required precise synthesis to avoid potential scrambling during the synthesis of porphyrins. Two typical pathways are nowadays used for constructing porphyrins and porphyrinoids, i.e., acid-catalyzed intermolecular [m+n] condensation of linear oligopyrroles and intramolecular cyclization of oligopyrroles. In addition to the intermolecular condensation reactions for synthesizing porphyrinoids, Xie and coworkers investigated intramolecularly oxidative cyclization reactions for synthesizing porphyrinoids, which enriches the structural diversities of porphyrinoids. Recently, molecular topology of porphyrin arrays or oligomers has attracted considerable attention because of their unique aromaticity and related promising applications in materials science. In this respect, Song and coworkers constructed porphyrins arrays by using bromo- and borylporphyrins as the building blocks.