详细信息

A new triazole-maleimide resin via azide-alkyne click chemistry: Synthesis and characterization  ( SCI-EXPANDED收录 EI收录)  

文献类型:期刊文献

英文题名:A new triazole-maleimide resin via azide-alkyne click chemistry: Synthesis and characterization

作者:Wang, Xiaofei[1];Wan, Liqiang[1];Huang, Farong[1];Du, Lei[1]

机构:[1]E China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Specially Funct Polymer Mat & Related Tec, Shanghai 200237, Peoples R China

年份:2011

卷号:65

期号:2

起止页码:268

外文期刊名:MATERIALS LETTERS

收录:;EI(收录号:20104913462781);WOS:【SCI-EXPANDED(收录号:WOS:000286158000037)】;

基金:The authors gratefully acknowledge the financial support of the National High Technology Research and Development Program of China (Grant No. 2002AA305103) and the National Basic Research Program of China (Grant No. 5131101).

语种:英文

外文关键词:Azide-alkyne click chemistry; Triazole-maleimide; Polymers; Thermal properties

摘要:Copper-catalyzed Azide-Alkyne Cycloaddition (CuAAC) was used to synthesize a new series of maleimides with triazole ring moieties (triazole-maleimides, TA-MIs). The physical and thermal properties of the obtained TA-MIs were studied. The TA-MIs showed good solubility in non-proton strong polar solvents such as DMF, DMAc and NMP. The polymerization of TA-MIs can be carried out at a temperature ranged from 140 degrees C to 250 degrees C. T-d5 of the resulted poly(TA-MIs) reached 335-345 degrees C under nitrogen. (C) 2010 Elsevier B.V. All rights reserved.

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