文献类型：期刊文献

英文题名：The influence of Sb₂O₃ addition on the properties of low-melting ZnO-P₂O₅ glasses

作者：Zhang, Bing[1];Chen, Qi[1,2];Song, Li[2];Li, Huiping[2];Hou, Fengzhen[2]

机构：[1]E China Univ Sci & Technol, Minist Educ, Key Lab Ultrafine Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Dept Inorgan Mat, Shanghai 200237, Peoples R China

年份：2008

卷号：91

期号：6

起止页码：2036

外文期刊名：JOURNAL OF THE AMERICAN CERAMIC SOCIETY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000256410700044)】；

语种：英文

摘要：The influence of 0-16 mol% Sb2O3 substitution for P2O5 on the properties of ZnO-P2O5 glasses has been investigated. It was shown that Sb2O3 could participate in the glass network and thermal stability of the glasses decreased with increasing Sb2O3 content. Glass transition temperature T-g, softening temperature T-s, and water durability all decreased firstly (up to 6 mol% Sb2O3 added) and then increased. Substitution of 12 mol% Sb2O3 led to a 16 degrees C decrease in T-g and 30 degrees C decrease in Ts, and weight loss of the glass was only 0.42 mg/cm(2), which is similar to 11 times lower than that of the glass without Sb2O3 after immersion in deionized water at 90 degrees C for 1 day. The glass containing 12 mol% Sb2O3 might be a substitute for Pb-based glasses in some applications.