文献类型：期刊文献

英文题名：Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid acid

作者：Wang, Jianjian[1];Xu, Wenjie[1];Ren, Jiawen[1];Liu, Xiaohui[1];Lu, Guanzhong[1];Wang, Yanqin[1]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

年份：2011

卷号：13

期号：10

起止页码：2678

外文期刊名：GREEN CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000295579700007)】；

基金：This project was supported financially by the National Basic Research Program of China (No. 2010CB732306), the National Natural Science Foundation of China (No. 20973058), the Commission of Science and Technology of Shanghai Municipality (10XD1401400) and the Fundamental Research Funds for the Central Universities.

语种：英文

摘要：A novel carbon-based solid acid, which was prepared by a facile and eco-friendly approach from glucose and p-toluenesulfonic acid (TsOH), was used to catalyze fructose dehydration into 5-hydroxymethylfurfural (HMF) for the first time and exhibits excellent catalytic performance. As high as 91.2% yield of HMF was achieved in dimethyl sulfoxide (DMSO) at 130 degrees C after only 1.5 h. Besides, this catalyst also displayed a good reusability.