文献类型：期刊文献

英文题名：NiCl2(PCy3)2-catalyzed hydrodefluorination of fluoroarenes with LiAl(O-t-Bu)3H

作者：Xiao, Juan[1];Wu, Jingjing[2];Zhao, Wenwen[1];Cao, Song[1]

机构：[1]E China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China;[2]Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China

年份：2013

卷号：146

起止页码：76

外文期刊名：JOURNAL OF FLUORINE CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000316588000012)，CCR-EXPANDED(收录号:WOS:000316588000012)】；

基金：We are grateful for financial supports from the National Natural Science Foundation of China (Grant Nos. 21072057, 21272070), the Key Project in the National Science & Technology Pillar Program of China in the twelfth five-year plan period (2011BAE06B05), the National Basic Research Program of China (973 Program, 2010CB126101), and the National High Technology Research and Development Program of China (863 Program, 2011AA10A204).

语种：英文

外文关键词：Hydrodefluorination; Nickel-based catalyst; Lithium tri-t-butoxyaluminium hydride; Fluoroarenes

摘要：A highly efficient and practical approach to the hydrodefluorination of C-F bond in fluoroarenes in the presence of 5 mol% NiCl2(PCy3)(2) with lithium tri-t-butoxyaluminium hydride (LiAl(O-t-Bu)(3)H) under mild conditions has been developed. (C) 2012 Elsevier B.V. All rights reserved.